Dalton Trans. 2026 Sep 17. doi: 10.1039/d6dt01884j. Online ahead of print. ABSTRACT The metalloenzymes manganese superoxide dismutase (MnSOD) and manganese lipoxygenase (MnLOX) both use a MnIII-hydroxo/MnII-aqua redox couple to mediate concerted proton-electron transfer (CPET) reactions with their biological substrates. Structural studies of these enzymes indicate hydrogen-bonding with the hydroxo/aqua ligands that presumably modulates the CPET…

Artif Life. 2026 Sep 15:1-33. doi: 10.1162/ARTL.a.490. Online ahead of print. ABSTRACT The Zoetic Engineering Grand Challenge is a proposal to catalyse work in the field of Cyber-Bio-Physical Systems by attacking the goal of creating a Living Skyscraper. This work builds upon that original idea, introducing the concept of the Zoetic Arcology: a proposal for…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…

ACS Appl Mater Interfaces. 2026 Sep 14. doi: 10.1021/acsami.6c12503. Online ahead of print. ABSTRACT A cytochrome P450-mimetic monodispersed Fe-porphyrin-based porous framework is designed and synthesized via a FeCl3-assisted Friedel-Crafts reaction, to combine the advantages of heterogeneous systems with enzymatic reactivity. Specifically, the Fe-porphyrin site in this material mimics the heme-center in cytochrome P450, which efficiently…